You should find a business partner. Someone who brings something different to the table. For example I have no programming experience, though I have manage to create successful startups. I bring marketing, leadership, creativity, direction, sales, and all other things not related to web design or programming to the table. You should find someone like that who can handle all the other work, therefore you don't have to stress out about anything not dealing with programming. Most startups have 2-3 partners. One of them are like me, another is a programmer, and the last (optional) is the designer.
Put together your ideas. Think it out, will it become profitable, how long will it take to grow a fan base, etc etc. Then start working on it. You don't need to devote 5 hours a day. I have a family too so I understand what you're going through. There's 24 hours in a day and I know you can at least spend 1 hour programming at home, or maybe just go to the library and do it there so there are no distractions. If you can devote 1hr a day of programming to your idea you would be surprised at how fast it will come along. Anything is better than nothing. Don't let excuses hold you back.